全文获取类型
收费全文 | 5848篇 |
免费 | 573篇 |
国内免费 | 155篇 |
专业分类
测绘学 | 245篇 |
大气科学 | 689篇 |
地球物理 | 2083篇 |
地质学 | 2325篇 |
海洋学 | 326篇 |
天文学 | 423篇 |
综合类 | 187篇 |
自然地理 | 298篇 |
出版年
2022年 | 8篇 |
2021年 | 17篇 |
2020年 | 15篇 |
2019年 | 16篇 |
2018年 | 446篇 |
2017年 | 384篇 |
2016年 | 277篇 |
2015年 | 160篇 |
2014年 | 132篇 |
2013年 | 142篇 |
2012年 | 667篇 |
2011年 | 437篇 |
2010年 | 142篇 |
2009年 | 183篇 |
2008年 | 160篇 |
2007年 | 134篇 |
2006年 | 158篇 |
2005年 | 860篇 |
2004年 | 889篇 |
2003年 | 671篇 |
2002年 | 192篇 |
2001年 | 87篇 |
2000年 | 64篇 |
1999年 | 25篇 |
1998年 | 19篇 |
1997年 | 25篇 |
1996年 | 16篇 |
1995年 | 12篇 |
1994年 | 13篇 |
1993年 | 10篇 |
1992年 | 5篇 |
1991年 | 15篇 |
1990年 | 15篇 |
1989年 | 11篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 9篇 |
1979年 | 4篇 |
1978年 | 14篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1974年 | 10篇 |
1973年 | 14篇 |
1965年 | 6篇 |
1962年 | 4篇 |
排序方式: 共有6576条查询结果,搜索用时 62 毫秒
51.
Katharina?Marquardt Elena?Petrishcheva Emmanuel?Gardés Richard?Wirth Rainer?Abart Wilhelm?Heinrich 《Contributions to Mineralogy and Petrology》2011,162(4):739-749
Yb-Y inter-diffusion along a single grain boundary of a synthetic yttrium aluminium garnet (YAG) bicrystal has been studied
using analytical transmission electron microscopy (ATEM). To investigate the diffusion, a thin-film containing Yb as the diffusant
was deposited perpendicular to the bicrystal grain boundary by pulsed laser deposition (PLD). Structural properties and their
change with time in both the diffusant source and the grain boundary are reported. The diffusion profiles are incorporated
in a numerical diffusion model, which is applied to determine the grain boundary diffusion coefficient, D
gb
, at 1.723 K it is equal to 3 × 10−15 m2/s. We find that grain boundary diffusion is 4.85 orders of magnitude faster than volume diffusion, which was determined from
the same diffusion experiment. This result is discussed in the context of special versus general grain boundaries. Finally,
we successfully tested the capability of synchrotron-based nano-X-ray fluorescence analysis to map micro-chemical patterns
in two dimensions with sub-micrometre resolution. 相似文献
52.
Michael Zech Nikolai Pedentchouk Katharina Leiber Slobodan B. Markovi? 《Geochimica et cosmochimica acta》2011,75(17):4917-4928
During the last decade, compound-specific hydrogen isotope analysis of plant leaf-wax and sedimentary n-alkyl lipids has become a promising tool for paleohydrological reconstructions. However, with the exception of several previous studies, there is a lack of knowledge regarding possible effects of early diagenesis on the δD values of n-alkanes. We therefore investigated the n-alkane patterns and δD values of long-chain n-alkanes from three different C3 higher plant species (Acer pseudoplatanus L., Fagus sylvatica L. and Sorbus aucuparia L.) that have been degraded in a field leaf litterbag experiment for 27 months.We found that after an initial increase of long-chain n-alkane masses (up to ∼50%), decomposition took place with mean turnover times of 11.7 months. Intermittently, the masses of mid-chain n-alkanes increased significantly during periods of highest total mass losses. Furthermore, initially high odd-over-even predominances (OEP) declined and long-chain n-alkane ratios like n-C31/C27 and n-C31/C29 started to converge to the value of 1. While bulk leaf litter became systematically D-enriched especially during summer seasons (by ∼8‰ on average over 27 months), the δD values of long-chain n-alkanes reveal no systematic overall shifts, but seasonal variations of up to 25‰ (Fagus, n-C27, average ∼13‰).Although a partly contribution by leaf-wax n-alkanes by throughfall cannot be excluded, these findings suggest that a microbial n-alkane pool sensitive to seasonal variations of soil water δD rapidly builds up. We propose a conceptual model based on an isotope mass balance calculation that accounts for the decomposition of plant-derived n-alkanes and the build-up of microbial n-alkanes. Model results are in good agreement with measured n-alkane δD results. Since microbial ‘contamination’ is not necessarily discernible from n-alkane concentration patterns alone, care may have to be taken not to over-interpret δD values of sedimentary n-alkanes. Furthermore, since leaf-water is generally D-enriched compared to soil and lake waters, soil and water microbial n-alkane pools may help explain why soil and sediment n-alkanes are D-depleted compared to leaves. 相似文献
53.
Emma J. Pearson Steve Juggins Jan Weckström David B. Ryves Roland Schmidt 《Geochimica et cosmochimica acta》2011,75(20):6225-6238
Quantitative climate reconstructions are fundamental to understand long-term trends in natural climate variability and to test climate models used to predict future climate change. Recent advances in molecular geochemistry have led to calibrations using glycerol dialkyl glycerol tetraethers (GDGTs), a group of temperature-sensitive membrane lipids found in Archaea and bacteria. GDGTs have been used to construct temperature indices for oceans (TEX86 index) and soils (MBT/CBT index). The aim of this study is to examine GDGT-temperature relationships and assess the potential of constructing a GDGT-based palaeo-thermometer for lakes. We examine GDGT-temperature relationships using core top sediments from 90 lakes across a north-south transect from the Scandinavian Arctic to Antarctica including sites from Finland, Sweden, Siberia, the UK, Austria, Turkey, Ethiopia, Uganda, Chile, South Georgia and the Antarctic Peninsula. We examine a suite of 15 GDGTs, including compounds used in the TEX86 and MBT/CBT indices and reflecting the broad range of GDGT inputs to small lake systems.GDGTs are present in varying proportions in all lakes examined. The TEX86 index is not applicable to our sites because of the large relative proportions of soil derived and methanogenic components. Similarly, the MBT/CBT index is also not applicable and predicts temperatures considerably lower than those measured. We examine relationships between individual GDGT compounds and temperature, pH, conductivity and water depth. Temperature accounts for a large and statistically independent fraction of variation in branched GDGT composition. We propose a GDGT-temperature regression model with high accuracy and precision (R2 = 0.88; RMSE = 2.0 °C; RMSEP = 2.1 °C) for use in lakes based on a subset of branched GDGT compounds and highlight the potential of this new method for reconstructing past temperatures using lake sediments. 相似文献
54.
Nb-Ta-Ti-bearing oxide minerals (Nb-Ta-bearing rutile, columbite-group minerals) represent the most common Nb-Ta host in topaz-albite granites and related rocks from the Krásno-Horní Slavkov ore district. Tungsten-bearing columbite-(Fe), W-bearing ixiolite, wodginite and tapiolite-(Fe) are extremely rare in these rocks. Rutile contains significant levels of Ta (up to 37?wt.% Ta2O5) and Nb (up to 24?wt.% Nb2O5), with Ta/(Ta?+?Nb) ratio ranging from 0.04 to 0.61. Columbite-group minerals are represented mostly by columbite-(Fe) and rarely by columbite-(Mn), with Mn/(Mn?+?Fe) ratio ranging from 0.23 to 0.94. The exceptionally rare Fe-rich, W-bearing ixiolite occurs only as inclusions in Nb-Ta-bearing rutile from quartz-free alkali-feldspar syenites (Vysoky Kámen stock). Wodginite was found only in the topaz-albite microgranite of gneissic breccia matrix that occurs in the upper most part of the Hub topaz-albite granite stock. In wodginite, the Mn/(Mn?+?Fe) ratio is 0.42?C0.51, whereas the coexisting tapiolite-(Fe) has a distinctly lower Mn/(Mn?+?Fe) ratio close to 0.06. 相似文献
55.
Contrasting tourmaline types from peraluminous granites: a case study from Moslava?ka Gora (Croatia)
Two texturally and chemically distinct types of tourmaline are found inside peraluminous granites of the Moslava?ka Gora, Croatia: nodular tourmaline in the two-mica granite and disseminated tourmaline in the cross-cutting leucogranite dykes. Both tourmaline types belong to alkali tourmaline group, nodular tourmaline being dravite to schorl and disseminated tourmaline corresponding to schorl. Comparison of characteristic parameters of nodular (Nt) and disseminated tourmaline (Dt) shows significant differences in #Fe (0.40?C0.65 for Nt vs. 0.74?C0.85 in Dt) along with variations in the calculated X-site vacancy (0.22?C0.37 pfu in Nt and 0.33?C0.44 in Dt) and ??/(??+Na) ratio (0.23?C0.40 in Nt and 0.34?C0.45 in Dt). Disseminated tourmaline from the MG leucogranites is regarded as an early crystallized magmatic phase, while the interstitial tourmaline from the cores of tourmaline nodules originated from more complex mineralogical and chemical interactions inside the two-mica granite melt. Major element gain (Mg) and loss (Fe, Ca, Na, K) for the ??idealized nodule?? (34 vol. % core + 66 vol. % halo) when compared to the host granite shows that the nodule??s volume is not a completely independent and closed system. Based on the observed characteristics, nodule??s halo can be considered as a ??transitional zone?? between the tourmaline-bearing core and the host granite, texturally and mineralogically related to the host two-mica granite, chemically being an integral part of the nodule??s volume at the same time. 相似文献
56.
Helena O?ahe?ová Ján O?ahe? Robert Pazúr Richard Hrivnák Milan Valachovi? 《Limnologica》2011,41(4):316-324
The aquatic vegetation of ?í?ov Lake in the Danube floodplain, which is listed in the Ramsar Convention, was investigated to address three main questions: (1) how have landscape composition and the structures of the lake and its buffer zone changed from the mid-20th century; (2) how have species richness and the abundance of the aquatic macrophyte assemblage in this lake ecosystem changed over the last 34 years; and (3) which landscape metrics can best explain these temporal changes for floating-leaved macrophytes? Two methodological approaches, remote sensing and botanical field surveys, were applied. Historical (1949, 1970, 1990) and contemporary (2006) aerial photographs were analysed to determine land cover. Landscape configuration and structure were analysed using eight landscape metrics selected in advance to measure spatio-temporal changes and the fragmentation of the lake ecosystem and its corresponding buffer zone. The species diversity, abundance and distribution of true aquatic macrophytes were surveyed eleven times in five survey stretches between 1973 and 2007.At the landscape level, a decrease in the area covered by floating-leaved macrophytes, as well as an increase in open water surface and fragmentation of the land cover classes in the lake ecosystem, were recorded from 1949 to 2006. Overall, 30 true aquatic macrophytes were found from 1973 to 2007. Species richness did not change considerably, but the abundance of aquatic species fluctuated over the years. Three groups of true aquatic vegetation, based on common structural characteristics, were found in 1973–1983, 1989–2002, and 2004–2007 over the last 34 years. The landscape metrics NP, PD, LPI, and SHDI, which all express patterns of landscape fragmentation mostly indicate temporal changes in floating-leaved macrophytes. 相似文献
57.
Bla?enka Gašparovi? Tamara DjakovacNataša Tepi? Danilo Degobbis 《Continental Shelf Research》2011,31(10):1149-1160
Surface-active organic substances (SAS), nutrients, chlorophyll a (Chl a), dissolved oxygen (O2), salinity (S) and temperature (T) were measured approximately monthly in the northern Adriatic Sea (NA) during two years. Results were elaborated for two stations of different trophic status. Exhaustive statistical examinations of measured variables were performed to contribute to better understanding of the processes and interdependence of the measured parameters. The results of those analyses allowed the region to be described based on several groups of data relevant for particular processes. Chl a appear to be independent parameter; orthosilicate, nitrite and ammonium represent the parameter group most relevant for regeneration processes; the second group includes nutrients dominant in freshwater inputs (orthophosphate and nitrate), while in the third group are parameters related to primary production processes (T, O2, organic phosphorus and SAS). Probably due to time lags between nutrient uptake and phytoplankton growth as well as between cells growth/division and SAS release, both, the correlation between nutrients and Chl a and the correlation between Chl a and SAS were not statistically significant. Although significantly higher nutrient and Chl a concentrations were found in the mesotrophic western part of the region in comparison to the oligotrophic eastern part, the SAS concentration differences were less marked. It is assumed that more OM is produced, but also at the same time remineralized, at the mesotrophic western part, leading to higher concentrations of regenerated nutrients there. Presence of different phytoplankton taxa and/or fractions (micro and nano) at the two stations may have also contributed to minimize the difference in SAS contents. Higher SAS acidities were noticed in the mesotrophic than in the oligotrophic part. 相似文献
58.
"5·12"汶川特大地震引发的次生山地灾害中以山体崩塌数量最多.本文在对国道213线都江堰至映秀段以及水磨支线公路边坡地震崩塌调查研究的基础上,分析总结了岩土体边坡的崩塌成灾模式、崩塌作用机理以及崩塌自组织临界(SOC)动力学特性.调查范围包括Ⅸ~Ⅺ度地震区,工点105个.对崩塌体方量、崩塌深度进行统计分析后发现,在Ⅸ度区崩塌体方量和崩塌深度都符合负幂律分布,呈现出明显的自组织临界动力学特性;而Ⅹ、Ⅺ度地震区不呈现该崩塌特性,其崩塌动力学性质受地震的强扰作用控制. 相似文献
59.
60.